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Multiferroic CoFe2O4-BiFeO3(CFO-BFO)core-shell nanofibers were synthesized by coaxial electrospinning.The spinel structure of CFO and perovskite structure of BFO were confirmed by X-ray diffraction and high resolution transmission electron microscopy.The core-shell configuration of nanofibers was verified by scanning electron microscopy and transmission electron microscopy images.