【摘 要】
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Spontaneous formation of ordered structures from amphiphilic molecules has attracted tremendous attentions in the last decades.Among the many different amphiphi
【机 构】
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DepartmentofphysicsandAstronomy,McMasterUniversity,Hamilton,OntarioCanadaL8S4M1
【出 处】
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第二届中国科学院应用化学学术研讨会——高分子科学分会
论文部分内容阅读
Spontaneous formation of ordered structures from amphiphilic molecules has attracted tremendous attentions in the last decades.Among the many different amphiphilic systems, block copolymers with their rich phase behavior and ordering transitions have become a paradigm for the study of structural self-assembly.For the simplest case of diblock copolymers, which are linear polymers composed of two different sub-chains (A and B blocks), a variety of ordered bulk phases, including lamellae, hexagonally-packed cylinders, body-centered-cubic spheres and a bicontinuous network structure called gyroid, are observed.Understanding the structures and phase transitions in block copolymers has been one of the most active research areas in polymer science in the past two decades.One of the achievements is the self-consistent field theory (SCFT), which provides a powerful framework for the study of ordered phase of block copolymers.
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