【摘 要】
：
本文利用2,2,2"-(((2,4,6-三甲基苯-1,3,5-三基)三(亚甲基))三(硫基))苯三甲酸配体和Na(NO3)进行自组装,合成了二维的金属—有机框架化合物。通过X-射线单晶衍射结构分析
【机 构】
：
中国石油大学(华东)化学系,山东,青岛,266580
论文部分内容阅读
本文利用2,2,2"-(((2,4,6-三甲基苯-1,3,5-三基)三(亚甲基))三(硫基))苯三甲酸配体和Na(NO3)进行自组装,合成了二维的金属—有机框架化合物。通过X-射线单晶衍射结构分析可知,配合物为单斜晶系,属于C 空间群。羧酸与金属钠之间的配位模式不同,使其形成双链,通过π-π堆积作用形成二维层状,因此整个配合物最终形成二维双链结构。此外还对这种配合物进行了X-射线粉末衍射,气体吸附,元素分析,热重分析和荧光分析等基本性质的研究。
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