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利用6,6-环戊烷基富烯与芳基锂作用形成的取代环戊二烯基锂,与双(环戊二烯基)四氯-μ-氧合二钛反应这一新的合成方法,制备了(η~5-环戊二烯基)[η~5-(1-(4-甲氧基苯基)环已烷基)环戊二烯基]二氯化钛(I).元素分析、核磁、红外、质谱分析确认合成产物为
The novel synthesis of substituted cyclopentadienyl lithium formed by the interaction of 6,6-cyclopentane-rich fullenes and aryllithium with bis (cyclopentadienyl) tetrachloro-μ-oxo-di-titanium (Η~5-cyclopentadienyl) [η~5- (1- (4-methoxyphenyl) cyclohexyl) cyclopentadienyl] titanium dichloride Elemental analysis, nuclear magnetic resonance, infrared and mass spectrometry confirmed that the synthesized product was