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The central Ⅴ atom in bis[6-methyl-4-hydroxy-3-quinolinecarboxylate] mono(oxo)mono-hydroxy-vanadi-um(Ⅴ) (1), synthesized by the hydrothermal treatment of ethyl 6-methyl-4-hydroxy-3-quinolinecarboxylate andV2O5, has a distorted octahedral coordination geom