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研究了制备苯膦酸－磷酸锆Ｚｒ（ＰＯ４Ｈ）２－ｎ（ＰＯ３Ｐｈ）ｎ的主要影响因素．在Ｆ－／Ｚｒ４＋＝１２和Ｈ３ＰＯ４／Ｚｒ４＋＝２０条件下，通过改变苯膦酸用量获得了ｎ＝０～２的系列单一晶相层状苯膦酸－磷酸锆，其热稳定性达４００℃以上．苯膦酸－磷酸锆的磺化试验表明层间苯环可被完全磺化，磺化产物Ｚｒ（ＰＯ４Ｈ）２－ｎ（ＰＯ３ＰｈＳＯ３Ｈ）ｎ具有丰富的酸性位，其热稳定性亦可达到３００℃以上．
The main factors affecting the preparation of phenylphosphonic acid-zirconium phosphate Zr (PO4H) 2-n (PO3Ph) n were studied. Under the conditions of F- / Zr4 + = 12 and H3PO4 / Zr4 + = 20, a series of single crystal phase layered phenylphosphonic acid-zirconium phosphate with n = 0 ~ 2 was obtained by changing the amount of phenylphosphonic acid and its thermal stability reached 400 ℃ the above. The sulfonation of phenylphosphonic acid-zirconium phosphate shows that the interlayer benzene ring can be completely sulfonated. The sulfonated product Zr (PO4H) 2-n (PO3PhSO3H) n has abundant acidic sites and its thermal stability can reach 300 ℃ the above.