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自从Pope等在1975和1976年分别制得有机膦、胂合钼聚多酸盐晶体以来,这类具有“柄状”的化合物以后又有报道。这一大类有机衍生物在催化、生物化学和医学上颇具应用价值。但预期的有机(月弟)合钼聚多酸盐晶体文献尚无报道。在水溶液中制备有机(月弟)合钨“柄状”物晶体,只得到了玻璃状化合物2(CN_3H_6)_2O·5(p-NO_2C_6H_4SbO_2)·5WO_3,(CN_3H_6)_2O·3C_6H_5SbO_2·3WO_3,4(CN_3H_6)_2O·9(p-CH_3C_6H_4SbO_2)·12WO_3以及3.5(CN_3H_6)_20·9(p-ClC_6H_4SbO_2)·12WO_3。并发现多种单芳基(月弟)酸与钼酸钠在水溶液中反应,也仅能生成液面
Since Pope and other organic phosphine, arsine molybdenum polyacid salt crystals were prepared in 1975 and 1976, respectively, such compounds have “handle-like” later reported. This large class of organic derivatives is of great catalytic, biochemical and medical value. However, there is no report on the expected organic (cousin) molybdate polycrystal salt crystals. In the aqueous solution, an organic (ct) tungsten compound was obtained, and only the glassy compound 2 (CN_3H_6) _2O.5 (p-NO_2C_6H_4SbO_2) · 5WO_3, (CN_3H_6) _2O · 3C_6H_5SbO_2 · 3WO_3,4 (CN_3H_6 ) _2O · 9 (p-CH_3C_6H_4SbO_2) · 12WO_3 and 3.5 (CN_3H_6) _20 · 9 (p-ClC_6H_4SbO_2) · 12WO_3. And found that a variety of single-aryl (Yue brother) acid and sodium molybdate reaction in aqueous solution, can only generate liquid