主要报道了用金橙Ｇ螯合负载形成树脂分离富集地质样品中贵金属Ｒｈ的方法。在最佳试验条件下Ｒｈ的回收率可达９５％～１０５％之间；其相对标准偏差为４．４９％；百分相对误差较小，为－２．４％；方法无系统误差；用硫脲洗脱，该负载形成树脂不被破坏，重复使用５次，树脂均未见异常，均能定量回收，回收率在９８．５％～１０４％之间，符合要求。说明，这种负载形成树脂也较稳定，也可用于实际地质样品中微量贵金属的分离富集 This paper mainly reports the method of separating and enriching precious metal Rh in geological samples by gold chelated orange G chelating resin. Under the optimal experimental conditions, the recovery rate of Rh can reach 95% -105%, the relative standard deviation is 4.49%, the relative percentage error is small, which is -2.4%; the method has no systematic error; Thiourea elution, the load-forming resin is not damaged, repeated use of 5 times, the resin were not abnormal, can be quantitative recovery, the recovery rate of 98.5% to 104%, in line with the requirements. This shows that this load-forming resin is also relatively stable and can also be used for the separation and enrichment of trace precious metals in actual geological samples