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本文测定了乙酰丙酮-meso-四-(对甲氧基苯基)卟啉稀土络合物Ln(P-CH_3O)TppAcac[Ln: Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu; (P-CH_3O)Tpp: meso四-(对甲氧基苯基)卟啉;Acac:乙酰丙酮]的红外和拉曼光谱。红外光谱在NICOLETFT IR7199上测量,范围为100～4000cm~(-1)。100～400cm~(-1)范围内样品用聚乙烯压片,400～4000cm~(-1)内样品用溴化钾压片。拉曼光谱在Ramanor HG2S上测量,激发线波长为4579,功率50毫瓦,固体样品磨碎后压抹在圆柱状样品池的顶部,旋转样品池,90°角照
In this paper, the effects of acetylacetone-meso-tetrakis- (p-methoxyphenyl) porphyrin rare earth complex Ln (P-CH 3 O) TppAcac [Ln: Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu; (P-CH 3 O) Tpp: meso tetra- (p-methoxyphenyl) porphyrin; Acac: acetylacetone]. Infrared spectra were measured on NICOLETFT IR7199 in the range of 100-4000 cm -1. The samples in the range of 100 ~ 400cm ~ (-1) were compressed with polyethylene and the samples in 400 ~ 4000cm ~ (-1) were compressed with potassium bromide. The Raman spectrum was measured on a Ramanor HG2S with an excitation line wavelength of 4579 and a power of 50 mW. The solid sample was crushed and pressed onto the top of a cylindrical sample cell. The sample cell was rotated, rotated 90 °