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A novel Cd(Ⅱ) coordination polymer, {[Cd3(tzo)2(suc)(H2O)6]·(suc)}n (Htzo = 1,2, 4-triazole, H2suc = succinic acid), has been synthesized from the reaction of aqueous solution of Cd(NO3)2·4H2O with a 1:1 mixture of disodium succinate and 1,2,4-triazole by hydrothermal tech-niques, and structurally characterized by X-ray analysis and spectral techniques. To the best of our knowledge, among the few documented triazole-cadmium coordination polymers, this complex presents a novel configuration. The deprotonated 1,2,4-triazole is in tridentate and succinate in bis-chelate modes to link the Cd(Ⅱ) centers, generating a 2-D grid-like network topology. Ther-mogravimetric analysis results show that the framework architecture is a stable porous material. The fluorescent emission has also been discussed.
A novel Cd (Ⅱ) coordination polymer, {[Cd3 (tzo) 2 (suc) (H2O) 6] (suc)} n (Htzo = 1,2,4-triazole, H2suc = succinic acid) from the reaction of aqueous solution of Cd (NO3) 2 · 4H2O with a 1: 1 mixture of disodium succinate and 1,2,4-triazole by hydrothermal tech-niques, and structurally characterized by X-ray analysis and spectral techniques. To the best of our knowledge, among the few documented triazole-cadmium coordination polymers, this complex presents a novel configuration. The deprotonated 1,2,4-triazole is in tridentate and succinate in bis-chelate modes to link the Cd (II) centers , generating a 2-D grid-like network topology. Ther-mogravimetric analysis results show that the framework architecture is a stable porous material. The fluorescent emission has also been discussed.