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本文采用脉冲反应动力学方法研究了环己烷在 ZnZSM-5沸石上的反应特性,证明环己烷在该沸石上的反应为表观一级反应,测定了390～450℃区间的有关动力学参数,并结合产物分布讨论了反应过程的机理.
In this paper, the reaction kinetics of cyclohexane on ZnZSM-5 zeolite was studied by pulse reaction kinetics. It was proved that the reaction of cyclohexane on this zeolite was an apparent first-order reaction. The kinetics of the reaction at 390-450 ℃ was determined. Parameters, combined with product distribution discussed the reaction mechanism.