本文合成了十三种未见报道的稀土二茂铁丙烯酸配合物,并经元素分析及红外光谱和热谱分析,确定了它们的组成.此外,还测量了部分配合物的X-射线粉末衍射图,对其结构异构体进行了分类.1 稀土配合物的制备二茂铁丙烯酸(HL)是以二茂铁为原料,参照文献[1]和[2]合成的.氯化稀土由纯度大于99.9%的氧化物制备,稀土配合物是在无水乙醇溶液中,按摩尔比RE∶HL=1∶3计量,由RECl_3和 Thirteen kinds of rare-earth ferrocene-acrylic acid complexes were synthesized in this paper, and their compositions were confirmed by elemental analysis, IR and thermal analysis.In addition, X-ray powder diffraction Figure 1, the structural isomers were classified.1 Preparation of rare earth complexes Ferrocene acrylic acid (HL) is based on ferrocene, with reference to the literature [1] and [2] synthesized rare earth chloride from the purity Greater than 99.9% oxide prepared rare earth complexes in absolute ethanol solution, according to the molar ratio of RE: HL = 1: 3 by RECl_3 and