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A doublely-doped layered double hydroxide (LDH) film was produced on an anodized magnesium alloy AZ31.The Ce-doped Mg-Al LDH film was prepared by in-situ hydrothermal treatment method,and the intercalation of vanadate was realized by ion-exchange reaction.The structure,morphology and composition of as-prepared LDH film were investigated by X-ray diffractometer,field-emission scanning electronic microscope and energy dispersive spectrometry.Results indicated that a uniform and compact LDH film was formed and the intercalation ofCe3+ and vanadate would change the crystal structure of LDHs.The results of the potentiodynamic polarization,electrochemical impedance spectra,hydrogen evolution and corrosion weight loss tests showed the Ce3+ and vanadate anions significantly improve the impedance of LDH film,and the active double-doped LDH film could effectively protect the magnesium substrate from corrosion.