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随着学科之间相互交叉渗透的发展,兼有无机材料的功能性和有机材料的可加工型的新型杂化材料显示出了巨大的应用前景。本篇论述介绍本研究组在过去几年里,将多金属氧酸盐簇(Polyoxometalates)与我们熟知的聚合物通过共价键相连接制备杂化物(Polyoxometalate-Polymer Hybrids,PPHs)的研究结果,目的是在保证POMs簇合物特殊功能的前提下,还赋予杂化物良好的可加工性能,开发高附加值的功能杂化材料。通过对含PPHs的合成和超分子聚集体自组装行为的研究工作,将POMs簇合物化学、聚合物化学和超分子科学的相关知识融合在一起,并在这三个传统研究方向的交叉点上开辟了一个新的突破领域,该研究成果为先进功能材料的制备提供了一个新的思路。
With the development of interdisciplinary penetration among disciplines, new hybrid materials that combine both the functionality of inorganic materials and the machinability of organic materials have shown great promise. This review presents the findings of our group in the past few years in the preparation of polyoxometalate-polymer hybrids (PPHs) by covalently linking polyoxometalates with our well-known polymers, The purpose is to assure the good machinability of the hybrid under the premise of guaranteeing the special functions of the POMs cluster, and to develop the functional hybrid material with high added value. Through the research work on the synthesis of PPHs and the self-assembly behavior of supramolecular aggregates, the related knowledge of cluster chemistry, polymer chemistry and supramolecular science of POMs was merged together. At the intersection of these three traditional research directions Has opened up a new breakthrough area, the research results provide a new idea for the preparation of advanced functional materials.