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本文合成了Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Cu(Ⅱ)大环配合物及其溴碘加成物,研究了远红外和Raman光谱,对MN_4局部进行了伸缩振动的简正坐标分析,求得了各化合物的键角和伸缩力常。通过Raman光谱初步确定了溴碘的存在形式。对溴碘加成物的叠层结构和各化合物的成键进行了讨论。
In this paper, macrocyclic complexes of Co (Ⅱ), Ni (Ⅱ), Cu (Ⅱ) and Cu (Ⅱ) were synthesized and their bromine and iodine adducts were synthesized. The far-infrared and Raman spectra were studied. Jane coordinate analysis, obtained the compounds of the bond angle and stretching force often. The existence of bromoiodide was determined by Raman spectroscopy. The lamination structure of bromo-iodine adducts and the bonding of various compounds were discussed.