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本文综述了近几年来手性金属卟啉配合物在主客体化学、立体催化及光电化学领域的性能研究成果。分析了在主客体化学中手性卟啉作为分子识别反应主体所具有的结构特征;介绍了模拟生物大分子的功能时手性卟啉所反映出的识别机制;评述了手性卟啉对苯乙烯及其衍生物的环丙烷化、羟基化及氨化等催化反应中所展示出的对映选择性和催化稳定性;概括了手性卟啉配合物在模拟植物光合成反应和制作新型光学材料方面所具有的光电性能。最后总结了手性卟啉研究成果的应用范围,并展望了手性卟啉在催化氧化方面的研究和发展方向。
This review summarizes the research results of the properties of chiral metalloporphyrins in the fields of host-guest chemistry, stereocatalysis and photoelectrochemistry in recent years. The structural characteristics of chiral porphyrin as the main body of molecular recognition reaction in host-guest chemistry were analyzed. The recognition mechanism reflected by chiral porphyrin when the function of biological macromolecule was simulated was introduced. The effects of chiral porphyrin on benzene Ethylene and its derivatives cyclopropanation, hydroxylation and ammoniation and other catalytic reactions demonstrated enantioselectivity and catalytic stability; summarized chiral porphyrin complexes in the simulation of plant photosynthetic reaction and the production of new optical materials Aspects of the photoelectric properties. Finally, the application of the research results of chiral porphyrins is summarized, and the research and development of chiral porphyrins in the field of catalytic oxidation are prospected.