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用过氧化物法合成了[Co(appma)(amp)Cl][ZnCl4](appma=N-(2-氨丙基)-2-吡啶甲胺,amp=2-(氨甲基)吡啶)体系配合物.元素分析与13C1、H NMR检测表明,配合物是标题体系中的二异构体且配合物阳离子中可能具有C—H…π结构.
[Co (appma) (amp) Cl] [ZnCl4] (appma = N- (2-aminopropyl) -2- picolylamine, amp = 2- (aminomethyl) pyridine) was synthesized by the peroxide method. Elemental analysis and 13C1, H NMR showed that the complex was a diastereomer in the title system and the C-H ... π structure might exist in the complex cation.