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5. Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers

Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：lequ123123

【摘 要】

：

The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from th

【作 者】

：

Xu Dong LIU Meng Xian DING Lia 

【机 构】

：

State Key Laboratory of Polymer Physics and Chemistry

【出 处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

Asymmetric catalysis chiral polymers BINOL 

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The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from these polymers and applied to the asymmetric reaction of Et2Zn with benzaldehyde. The products are obtained in good yields with moderate enantioselectivities.

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