Strongly coupled N-doped carbon/Fe3O4/N-doped carbon hierarchical micro/nanostructures for enhanced

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A strong interface coupling is of vital importance to develop metal oxide/carbon nanocomposite anodes for next-generation lithium ion batteries.Herein,a rational N-doped carbon riveting strategy is designed to boost the lithium storage performance of Fe3O4/N-doped carbon tubular structures.Polypyrrole (PPy) has been used as the precursor for N-doped carbon.N-doped carbon-riveted Fe3O4/N-doped carbon (N-C@Fe3O4@N-C) nanocomposites were obtained by pyrolysis of PPy-coated FeOOH@PPy nanotubes in Ar atmosphere.When tested as an anode for LIBs,the N-C@Fe3O4@N-C displays a high reversible discharge capacity of 675.8mA h g-1 after 100 cycles at a current density of 100mA g-1 and very good rate capability (470 mA h g-1 at 2 A g-1),which significantly surpasses the performance of Fe3O4@N-C.TEM analysis reveals that after battery cycling the FeOx particles detached from the carbon fibers for Fe3O4@N-C,while for N-C@Fe3O4@N-C the FeOx particles were still trapped in the carbon matrix,thus preserving good electrical contact.Consequently,the superior performance of N-C@Fe3O4@N-C is attributed to the synergistic effect between Fe3O4 and N-doped carbon combined with the unique structure properties of the nanocomposites.The strategy reported in this work is expected to be applicable for designing other electrode materials for LIBs.
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