电合成技术以其无污染等特性在有机合成领域越来越受人们的重视。直接有机电合成方法可能存在反应速度慢、能耗较大以及电极受干扰等问题,而间接有机电合成方法可以弥补这些不足。本系列报道分三部分介绍间接有机电合成的原理及其应用。本文报道第一部分内容,主要论述间接有机电合成的原理和方法。 Electrosynthesis technology with its pollution-free properties in the field of organic synthesis more and more attention. Direct organic electro-synthesis methods may have problems such as slow reaction rate, high energy consumption and electrode interference, and indirect organic electro-synthesis methods can make up for these shortcomings. This series of reports is divided into three parts introduces the principle of indirect organic electro-synthesis and its application. This article reports the first part, mainly discusses the principle and method of indirect organic electro-synthesis.