【摘 要】
:
Catalytic co-cracking of Fischer-Tropsch(FT)light distillate and methanol combines highly endothermic olefin cracking reaction with exothermic methanol conversi
【机 构】
:
Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology,College o
论文部分内容阅读
Catalytic co-cracking of Fischer-Tropsch(FT)light distillate and methanol combines highly endothermic olefin cracking reaction with exothermic methanol conversion over ZSM-5 catalyst to produce light olefins through a nearly thermoneutral process.The kinetic behavior of co-cracking reactions was investigated by different feed conditions: methanol feed only,olefin feed only and co-feed of methanol with olefins or F-T distillate.The results showed that methanol converted to C2-C6 olefins in first-order parallel reaction at low space time,methylation and oligomerization-cracking prevailed for the co-feed of methanol and C2-C5 olefins,while for C6-C8 olefins,monomolecular cracking was the dominant reaction whether fed alone or co-fed with methanol.For FT distillate and methanol co-feed,alkanes were almost un-reactive,C3-C5 olefins were obtained as main products,accounting for 71 wt%for all products.A comprehensive co-cracking reaction scheme was proposed and the model parameters were estimated by the nonlinear least square method.It was verified by experimental data that the kinetic model was reliable to predict major product distribution for co-cracking of FT distillate with methanol and could be used for further reactor development and process design.
其他文献
The nanophotocatalysts were synthesized in four stages and evaluated by FTIR,FESEM and VSM analysis.The influ-ence of nanofluids containing functionalized magne
The dynamic analysis and optimal design of reactive extraction are challenging due to high nonlinearity of model equations and tough decision of judging criteri
A new polymeric adsorbent with highly hypercrosslinked structure was developed for the removal of VOCs from polluted air.The purpose of this work is to obtain t
Hybrid membranes combining the merits of both polymer matrices and fillers have drawn extensive attention.The rational design of polymer-filler interface in hyb
Fouling resistance of ultrafiltration(UF)membranes is critical for their long-term usages in terms of stable per-formance,so convenient approaches to prepare fo
Gas-liquid mass transfer of rotating disk reactor was studied in CO2 absorption using 1,8-diazabicyclo-[5.4.0]-undec-7-ene(DBU)-glycerol solution as solvent.Eff
提出应用最优拉丁超立方抽样的方法并结合响应面模型和带精英策略的非支配排序遗传算法(NSGA–II算法)实现注射工艺多目标优化,缩短寻找最优工艺参数的时间,提高塑件生产效率
Thin film composite(TFC)membranes represent a highly promising platform for efficient nanofiltration(NF)processes.However,the improvement in permeance is impede
Investigation was made on the efficiency of two commercial membranes in removing via forward osmosis(FO)the low molecular weight organic compounds typical of co
An efficient catalyst SO42--TiO2(ST)from industrial metatitanic acid has been successfully prepared to catalyze hydrolysis of ball-milling cellulose.The results