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The title compound Cd(Eim)3Cl2 (Eim=N-ethylimidazole) I has been synthesized and structurally characterized by single-crystal X-ray diffraction. The compound crystallizes in the monoclinic system, space group P21 with a=8.0460(16), b=29.186(6), c=8.8960(18), β=100.06(3)°, C15H24CdCl2N6, Mr=471.71,V=2056.9(7)3, Z=4, Dc=1.523 g/cm3, μ=1.330 mm-1, F(000)=952, the final R=0.0455 and wR=0.0723. The title compound crystallizes with two molecules in the asymmetric unit. Each CdII ion is coordinated by three Eim ligands and two Cl anions in a trigonal bipyramidal geometry in two molecules. The weak intermolecular C-H…Cl hydrogen bonds link the molecules into two independent hydrogen-bonded chains running along the c axis. According to the cyclic voltammogram measurement in H2O, the electrode reaction should be a quasi-reversible process.
The compound crystallizes in the monoclinic system, space group P21 with a = 8.0460 (16), and the structural compound Cd (Eim) 3Cl2 (Eim = N-ethylimidazole) I has been synthesized and structurally characterized by single- B = 29.186 (6), c = 8.8960 (18) β, β = 100.06 (3) °, C15H24CdCl2N6, Mr = 471.71, V = 2056.9 (7) 3, Z = 4, Dc = 1.523 g / cm3, μ = 1.330 mm-1, F (000) = 952, the final R = 0.0455 and wR = 0.0723. The title compound crystallizes with two molecules in the asymmetric unit. Each CdII ion is coordinated by three Eim ligands and two Cl anions in a trigonal bipyramidal geometry in two molecules. The weak intermolecular CH ... Cl hydrogen bonds link the molecules into two independent hydrogen-bonded chains running along the c axis. According to the cyclic voltammogram measurement in H2O, the electrode reaction should be a quasi-reversible process .