这里,我们怀着极大的兴趣来回顾日益发展的矿物和熔体热力学,其原因不仅仅是因为该学科中观念和技术上的进步,而且还因为这样一个事实:日趋成熟的地球化学和岩石学理论使我们意识到平衡热力学还不足以用来描述地球化学过程中的机理.这方面的详细研究,需要不可逆热力学或者动力学理论,在许多情况下,还需要被研究体系的流体动力学理论. Here, with great interest, we review the growing thermodynamics of minerals and melts not only for conceptual and technological advances in the discipline, but also because of the fact that the increasingly mature geochemistry and rock The theory of learning leads us to realize that equilibrium thermodynamics is not enough to describe the mechanics of the geochemical process, and detailed studies in this area require irreversible thermodynamics or kinetic theory and, in many cases, the hydrodynamic theory of the system under study .