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在BaO/CaO重量比值为1/1~5/1的范围内,测定了锰铁合金脱磷剂BaO-CaO-(5%~15%)MnO2-(15%~20%)CaF2的熔点,结果表明:当CaF2含量为15%时,随熔剂中BaO/CaO比值增大,相应熔点降低,随MnO2%增大,熔点升高.当CaF2含量为20%时,在BaO/CaO重量比值为2/1~3/1的组成区域内,熔点突然升高.根据实验结果,推荐60%BaO-12%CaO-8%MnO2-20%CaF2为锰铁合金脱磷剂,该熔剂熔点低(~1250℃),BaO/CaO比值高(5/1).
The melting point of BaFiO3 (5% ~ 15%) MnO2- (15% ~ 20%) CaF2 was measured in the range of BaO / CaO weight ratio from 1/1 to 5/1. The results show that when the content of CaF2 is 15%, the melting point decreases with the increase of BaO / CaO ratio in the flux. As the content of MnO2 increases, the melting point increases. When the content of CaF2 is 20%, the melting point abruptly rises in the compositional area with BaO / CaO weight ratio of 2/1 ~ 3/1. According to the experimental results, 60% BaO-12% CaO-8% MnO2-20% CaF2 is recommended as a ferromanganese dephosphorization agent with a low melting point (~ 1250 ° C) and a high BaO / CaO ratio (5/1).