报告了可调催化氧化不同形态铜转化 ,现域一步制得硫酸铜新方法及反应机制的研究结果 ,表明 ,在优选的常温、常压温和条件下 ,应用自制的新型铜 铁 氧 (CFOL)催化剂催化氧化粗矿铜 ,干湿法铜冶炼后的“渣铜” ,以及其它不论何种形态铜的转化 ,可一步制得较高纯度 ,高收率 (摩尔分数x 98%以上 )的硫酸铜 ,得到了分子、离子、络合物的协同催化的物理化学新图象 ,CFOL起转输电子的电桥作用 ,合理地解释了实验结果 The results of the research on the new method and reaction mechanism of copper sulfate prepared by catalytic oxidation of different forms of Cu in a single step are reported. The results show that under the condition of normal room temperature and atmospheric pressure, Catalytic oxidation of crude copper ore, “slag copper” after wet-dry copper smelting, and other forms of copper conversion can be made in one step with higher purity and higher yield (molar fraction x 98%) of sulfuric acid Copper, obtained a new image of the co-catalytic physical and chemical reactions of molecules, ions and complexes, CFOL played the role of the bridge of the transfer of electrons, a reasonable explanation of the experimental results