【摘 要】
：
One 6-metal Zn-Nd complex [Zn2Nd4L2(OAc)10(OH)2(CH3OH)2] (1) with Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H2L) was construct
【机 构】
：
College of Chemistry and Materials Engineering,Zhejiang Key Laboratory of Carbon Materials,Wenzhou U
论文部分内容阅读
One 6-metal Zn-Nd complex [Zn2Nd4L2(OAc)10(OH)2(CH3OH)2] (1) with Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H2L) was constructed, and it has nanoscale rectangular structure (8×11×28?). Excited by ligand-centered absorption bands,1 shows NIR emission of Nd3+ion. Interestingly, 1 exhibits lanthanide luminescent response towards metal ions, especially to alkali metal ions (Li+, Na+and K+) at ppm level.
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