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The photostabilies of hexanitrostillbene(HNS)were studied at 1％wt.of photostabilizers.The photo-stabilizers of Chiguard BP-12(UV-531),ADK STAB LA-326(UV-326),ADK STAB LA-32(UV-P),Irganox 1010 and Everstab LS944 were used in this study.A photoreactor including a 30 W monochromatic UV lamp was used for investigation of photodegradations of solid HNS.The changes in surface area of HNS peak in HPLC chromatogram at time intervals of 2,4,6 and 8 h were used for calculation of kinetic rate constants of photodegradation process.The compound of UV-P photostabilizer was found to have the greatest effect on enhancing photostability for HNS among the investigated photostabilizers.The kinetic rate constants were obtained 6.2 × 10-2 and 4.1 × 10-2 h-1,respectively,for photodegradation process of HNS in absence and in presence of UV-P.