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利用3,3’,4,4’-偶氮苯四甲酸、邻菲啰啉与醋酸镉反应得到了一种新型超分子配合物[Cd(phen)3(]H2abtc).0.5(H4abtc).CH3OH(1)(phen=邻菲啰啉,H4abtc=3,3’,4,4’-偶氮苯四甲酸),并通过X-射线单晶衍射分析、元素分析和荧光光谱对它进行了表征。结果表明,配合物1的镉原子与三个邻菲啰啉的六个N配位构成一个扭曲的八面体结构,配体3,3’,4,4’-偶氮苯四甲酸未参与配位。分子间通过氢键构成了1D的Z字链结构,而1D链之间通过O-H…O和C-H…O形成2D的网络结构。
A novel supramolecular complex [Cd (phen) 3 (H2abtc) .0.5 (H4abtc) was synthesized by the reaction of 3,3 ’, 4,4’-azobenzenetetracarboxylic acid and 1,10-phenanthroline with cadmium acetate. CH3OH (1) (phen = phenanthroline, H4abtc = 3,3 ’, 4,4’-azobenzenetetracarboxylic acid) and subjected to X-ray single crystal diffraction analysis, elemental analysis and fluorescence spectroscopy Characterization. The results show that the complex of cadmium atoms and three three phenanthroline six N coordination to form a twisted octahedral structure, the ligand 3,3 ’, 4,4’-azobenzenetetracarboxylic acid is not involved Bit. Molecular hydrogen bonds form a 1D Z-chain structure, while 1D chains form 2D network structures through O-H ... O and C-H ... O bonds.