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从非水体系中制得了ＮＨ４ＺｎＰＯ４单晶，并用Ｘ射线测定了晶体结构．晶体属六方晶系，Ｐ６３空间群．晶胞参数：ａ＝１．０６８８（２）ｎｍ，ｃ＝０．８７０６（２）ｎｍ，Ｚ＝８，Ｄｃ＝２．７５１ｇ·ｃｍ－３．结构中的锌和磷均为四面体配位，且严格交替排列，无Ｚｎ＿Ｏ＿Ｚｎ和Ｐ＿Ｏ＿Ｐ联结方式．骨架中的氧均为桥氧．骨架结构中存在沿ｃ轴方向伸展的规则的六元环直孔道．与其它磷酸盐不同的是，我们在该晶体骨架中首次观察到直线型的Ｚｎ＿Ｏ＿Ｐ联结方式．
NH4ZnPO4 single crystals were prepared from non-aqueous system and the crystal structure was determined by X-ray diffraction. Crystal is a hexagonal system, P63 space group. Cell parameters: a = 1.0688 (2) nm, c = 0.8706 (2) nm, Z = 8 and Dc = 2.751 g · cm-3. The structure of zinc and phosphorus are tetrahedral coordination, and strictly arranged alternately, without Zn_O_Zn and P_O_P connection. The oxygen in the skeleton is bridge oxygen. There is a regular hexagonal ring straight channel extending in the c-axis direction in the skeleton structure. Unlike other phosphates, we first observed a linear Zn_O_P linkage in this crystal framework.