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Recently some new apparatuses have been developed to study the thermal decomposition and the photodecomposition mechanism of silver azide with some new experimental results. We anal- ysed the experimental results with ab initio calculations (CASSCF, valence CI, MC-CEPA, ACPF and CEPA), assigned the spectrum structure of AgN3, plotted the potential energy curves of AgN3 and reinterpreted the photodecomposition mechanism of silver azide. The poten- tial energy curves of the two lowest singlet and the two lowest triplet valence states of AgN3 a- long AgN-NN distance R2 show that the two singlet valence states are involved in the photodisso- ciation of AgN3, proved by the two peaks at 2. 18 and 2. 23 eV which are the results of the elec- tron transition from the ground state to the two singlet valence states respectively.
Recently some new diffraction have been developed to study the thermal decomposition and the photodecomposition mechanism of silver azide with some new experimental results. We anal- ysed the experimental results with ab initio calculations (CASSCF, valence CI, MC-CEPA, ACPF and CEPA) , assigned the spectrum structure of AgN3, plotted the potential energy curves of AgN3 and reinterpreted the photodecomposition mechanism of silver azide. The poten- tial energy curves of the two lowest singlet and the two lowest triplet valence states of AgN3 a-long AgN-NN distance R2 show that the two singlet valence states are involved in the photodisso-iation of AgN3, proved by the two peaks at 2. 18 and 2. 23 eV which are the results of the elec- tron transition from the ground state to the two singlet valence states respectively.