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本文采用林圣贤所提出的绝热近似理论,较详细地计算了不同机制所引起的速率常数。并用两种方法论证了为非康登近似所修正的Born-Oppenheimer耦合的跃迁速率常数与非谐耦合所引起的速率常数有相同的数量级。此外,本文还指出转动能级对科里奥利机制的速率常数有重要影响。
In this paper, Lin Shengxian proposed adiabatic approximation theory, a more detailed calculation of the rate constant caused by different mechanisms. Two methods are used to demonstrate that the rate constants of Born-Oppenheimer coupling as modified by non-condonian approximations are about the same order of magnitude as the rate constants caused by anharmonic coupling. In addition, we also point out that the rotational energy level has an important influence on the rate constant of the Coriolis mechanism.