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本文研究了一系列异碳核苷及其氟代衍生物的NMR谱,对~1HNMR,~19FNMR和~13CNMR谱进行了完全归属,并利用~19F-~1H和~19F-~13C之间的偶合常数讨论了~19F对~1H和~13CNMR谱的影响。
In this paper, the NMR spectra of a series of isonucleosides and their fluorinated derivatives have been studied. The ~ 1HNMR, ~ 19FNMR and ~ 13CNMR spectra have been completely assigned to each other. The ~ 19F- ~ 1H and ~ 19F- ~ 13C The coupling constants discussed the effect of ~ 19F on ~ 1H and ~ 13CNMR spectra.