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由芳香族酰氯或α,β-不饱和酰氯与十二羰基三铁-硫醇-三乙胺体系反应,制得了通式为[(μ-RS)(μ-R′CO)Fe,(CO)_6](A)的六个铁硫原子簇配合物,以及通式为((μ-RS)(μR″CH=CR′)Fe_2(CO)_6](B)的六个铁硫配合物。对两种类型的配合物生成的过程及转化进行了初步的讨论。
(Μ-RS) (μ-R’CO) Fe, (CO-COOH) and their derivatives were synthesized from aromatic acyl chloride or α, β-unsaturated acid chloride and dodecacarbonyltrisferri-thiol- ) [6] (A) and six iron-sulfur complexes of the general formula ((μR "CH) CR 2 Fe 2 (CO) 6] A preliminary discussion of the process and transformation of the two types of complexes was carried out.