Effect of Alloying Elements on the Quality of Hard Anodic Oxidation Film in Aluminum Alloy 6061

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the effect of different Mg/Si and Mn content on uniformity and consistence of anodic films of 6061 aluminum alloy was investigated by using hardness test,coating thickness test, optical microscopy (OM),scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results show that when Mg/Si is in the vicinity of 1.73 and Mn content is 0.14%, the uniformity of the anodic film is the best while the consistence of the anodic film is the best when Mg/Si is 1.88 and Mn content is 0.14%. Superfluous silicon and magnesium have a bad function on the uniformity of anodic films of 6061 aluminum alloy because of secondary phases but magnesium in the base material can be beneficial for the consistence of the anodic film due to formation of a protective, impermeable layer of MgO below the anodic film while plentiful excess silicon result in single Si and w(Cu4Mg5Si4Alx) to gather in the grain boundary, which makes rarefactions and discontinuity present. The uniformity and consistence of anodic films are improved by Mn content rising, which is caused by the decrease of needle-like Fe-rich and Mg2Si phases and the increase of bone-like Fe-rich phases. the effect of different Mg / Si and Mn content on uniformity and consistence of anodic films of 6061 aluminum alloy was investigated by using hardness test, coating thickness test, optical microscopy (OM), scanning electron microscopy (SEM) and energy dispersive X-ray The results show that when Mg / Si is in the vicinity of 1.73 and Mn content is 0.14%, the uniformity of the anodic film is the best while the consistence of the anodic film is the best when Mg / Si is 1.88 and Mn content is 0.14%. Superfluous silicon and magnesium have a bad function on the uniformity of anodic films of 6061 aluminum alloy because of the secondary phases but magnesium in the base material can be beneficial for the consistence of the anodic film due to formation of a protective, impermeable layer of MgO below the anodic film while plentiful excess silicon result in single Si and w (Cu4Mg5Si4Alx) to gather in the grain boundary, which makes rarefactions and discontinuity present. The uniformity and consistence of anodic films are improved by Mn content rising, which is caused by the decrease of needle-like Fe-rich and Mg2Si phases and the increase of bone-like Fe-rich phases.
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