静止弹燃烧热量计对含C、H、O及C、H、O、N的化合物可以给出精度非常高的实验结果,但对于含卤素、硫及金属的有机化合物,由于:(1)不能形成单一氧化态的末态产物;(2)不能形成平衡的气液两相分布;(3)末态产物在弹体与弹壁各部分不能均匀分布;所以在燃烧末态不能获得一个均匀稳定的热力学平衡态,因而得不到精密的实验结果。现在国内外采用的转动弹热量计由于当试样燃烧后可使氧弹同时沿水平轴和垂直轴转动,从而克服了上述困难,得到了稳定的热力学终态。目前转动弹燃烧量热法日益广泛地应用于含硫、 Static bomb combustion calorimeters can give very high accuracy results for compounds containing C, H, O and C, H, O, N, but for organic compounds containing halogens, sulfur and metals due to: (1) no (2) can not form a balanced gas-liquid two-phase distribution; (3) the final product in the missile body and the elastic wall can not be evenly distributed in various parts; so at the end of combustion can not get a uniform and stable Thermodynamic equilibrium state, and thus can not get the precise experimental results. At present, the rotating calorimetry adopted at home and abroad overcomes the above difficulties and obtains a stable thermodynamic final state because the oxygen bomb can make the oxygen bomb rotate along the horizontal axis and the vertical axis simultaneously when the sample is burned. At present, the rotary calorimeter burning calorimetry is increasingly used in sulfur-containing,