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研究了轴向配体对杯[6]芳烃-双金属卟啉仿P450酶模型催化环己烯环氧化反应的影响,并考察了反应的动力学规律,结合UV-vis监测反应的结果,提出了一种可能的反应机制.
The effects of axial ligands on the catalytic oxidation of cyclohexene with the calix [6] arene-bimetallic porphyrin-P450 enzyme model were investigated. The kinetics of the reaction was also investigated. The UV- Proposed a possible reaction mechanism.