论文部分内容阅读
过渡金属的羰基原子簇合物作为重要的催化剂,广泛应用于烯烃异构化、加氢、氢甲酰化、甲醇同系化等催化反应中。异核过渡金属簇十二羰基三钴(钅了)、十二羰基三钴铁及九羰基三钴均属于同一类型的簇合物,即类似四面体结构。
As an important catalyst, the carbonyl cluster of transition metal is widely used in the catalytic reaction of olefin isomerization, hydrogenation, hydroformylation and methanol homologation. Heteronuclear transition metal cluster dodecacarbonyl tricobalt (arsenic), dodecacarbonyl tricobaltite and nonacarbonyl tricobalt belong to the same type of cluster complexes, that is, similar tetrahedral structure.