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报道了一个新型草酸根桥联双核铜( )配合物[Cu2(L)2(μ-ox)](ClO4)2(1)(L=1,5,9-三氮环十二烷)的制备、表征、光谱和磁性质.配合物1中的2个铜离子之间存在非常强的反铁磁耦合作用(2J=-454cm-1).
A novel oxalate bridged binuclear copper (Cu2 (L) 2 (μ-ox)] (ClO4) 2 (1) (L = 1,5,9-triazacyclododecane) Preparation, Characterization, Spectra and Magnetic Properties There is a very strong anti-ferromagnetic coupling (2J = -454cm-1) between the two copper ions in complex 1.