In the supervised classification process of remotely sensed imagery, the quantity of samples is one of the important factors affecting the accuracy of the image classification as well as the keys used to evaluate the image classification. In general, the samples are acquired on the basis of prior knowledge, experience and higher resolution images. With the same size of samples and the same sampling model, several sets of training sample data can be obtained. In such sets, which set reflects perfect spectral characteristics and ensure the accuracy of the classification can be known only after the accuracy of the classification has been assessed. So, before classification, it would be a meaningful research to measure and assess the quality of samples for guiding and optimizing the consequent classification process. Then, based on the rough set, a new measuring index for the sample quality is proposed. The experiment data is the Landsat TM imagery of the Chinese Yellow River Delta on August 8th, 1999. The experiment compares the Bhattacharrya distance matrices and purity index ⊿ and ⊿x based on rough set theory of 5 sample data and also analyzes its effect on sample quality.