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本工作成功地合成了十四种稀土三氟醋酸盐,从而解决了各种稀土离子在POCl_3—SnCl_4或ZrCl_4体系中的溶解掺杂及消除水的猝灭作用问题.观察了十四种稀土离子对掺Nd~(3+)的POCl_3—P_2O_3Cl_4—SnCl_4混合体系的激光性能和荧光寿命的影响,得到了一些有规律性的数据.
In this work, fourteen kinds of rare earth trifluoroacetate were successfully synthesized, which solved the problem of dissolving and doping various rare earth ions in POCl_3-SnCl_4 or ZrCl_4 system and eliminating the quenching effect of water.Four kinds of rare earth Ion on the Nd ~ (3 +) POCl_3-P_2O_3Cl_4-SnCl_4 mixed system of laser performance and fluorescence lifetime, obtained some regular data.