【摘 要】
：
The reaction of 1-phenacylimidazole with W(CO)6 in a 1:1 molar ratio under irra- diation with a high-pressure Hg lamp mainly yielded the title compound (C29H26N
【机 构】
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Department of Chemistry and Chemical Engineering
【基金项目】
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国家自然科学基金;教育部科学技术研究项目;宜宾大学校科研和教改项目
论文部分内容阅读
The reaction of 1-phenacylimidazole with W(CO)6 in a 1:1 molar ratio under irra- diation with a high-pressure Hg lamp mainly yielded the title compound (C29H26N4O7W, Mr = 726.39), which is of orthorhombic, space group Pbca with a = 27.665(4), b = 7.7807(12), c = 27.803(4) (A), V = 5984.8(16) (A)3, Z = 8, Dc = 1.612 g/cm3, λ(MoKα) = 0.71073 (A), μ = .3.911 mm-1, F(000) = 2864, R = 0.0583 and wR = 0.1502 for 3356 observed reflections (I > 2σ(I)). The crystal structural analysis indicates that in the coordination geometry of tungsten, 1-phenacylimidazole acts as a monodentate ligand and two imidazole ligands locate in a cis-position.
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