The development of two-dimensional hybrid nanomaterial derived from MXenes as high performance electrode material is the key component for the advanced energy storage and conversion systems. In the past decades, MXene derived nanomaterials have attracted greatly interest in scientific activity and potential applications because of their unique synergistic properties such as high thermal stability, excellent electrical conductivity, large surface area, easy to handle and outstanding electro and photo chemical properties. This review is focused on the synthesis of hybrid nanomaterials from MXene (Ti3C2Tx) for renewable energy conversion and storage application including hydrogen evolution reaction, supercapacitor, lithium-ion batteries and photocatalysis. Finally, we also summarized the prospect and opportunities of novel two-dimensional hybrid nanomaterials derived MXene (Ti3C2Tx) for futuristic sustainable energy technology.