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采用角重叠理论的方法,计算了三棱柱和八面体以及介于两者之间配体场的d轨道分裂后的能级,由此解释了造成JahnTeller效应的原因是键角的变化,而非键长的变化
By using the method of angular overlap theory, the energy levels of the d-orbitals of the triangular prism and the octahedron and the ligand field between the two are calculated, which explains why the JahnTeller effect is caused by the change of bond angle instead of Key length changes