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A new terbium(Ⅲ) complex Tb(C20H14O3N)3(C12H8N2)(H2O)·H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 1,10-phenanthroline as ligands. Crystal data for the complex are as follows: triclinic, space group P1, a =11.6034(6), b = 1