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通过电导测定法对１２－钨磷酸的Ｈ＋迁移性进行了研究。结果表明１２－钨磷酸的Ｈ＋是可以迁 移的。在本实验条件下，迁移活化能和活化熵分别为３７．３ ｋＪ／ｍｏｌ和－１２１．１Ｊ／（ｍｏｌ·Ｋ）。非极性 和弱极性分子吸附对Ｈ＋迁移几乎无影响，而含有羟基的分子；如水和醇等吸附有利于促进Ｈ■的移 动。在后一种情况下，Ｈ＋的迁移主要按下述机理进行：Ｈ＋从Ｒ０Ｈ＋２（Ｒ＝Ｈ或烷基）转到同它以 氢键相连的ＲＯＨ上，这个分子又将其另一个Ｈ＋传到同它邻接的另外一个分子，以此继续下去。
H + mobility of 12-tungstophosphoric acid was investigated by conductivity measurement. The results show that H + of 12-tungstophosphoric acid is migratable. Under the experimental conditions, the activation energy and activation entropy of migration are 37.3 kJ / mol and -121.1 J / (mol · K), respectively. Non-polar and weak polar molecule adsorption has almost no effect on H + migration, while molecules containing hydroxyl groups; such as water and alcohol adsorption is conducive to promoting the movement of H ■. In the latter case, the transfer of H + takes place essentially as follows: H + is transferred from ROH + 2 (R = H or alkyl) to its hydrogen-bonded ROH, which in turn propagates its other H + The other molecule adjacent to it continues.