论文部分内容阅读
A novel blue luminescent mercury ( Ⅱ ) complex of 2,6-bis ( benzimidazolyl ) pyridine (L) was synthesized. In solid state, this complex has the formula [ Hg(L) Cl2 ] · 2DMF( 1 ). The molecular structures of both the ligand and the complex were determined by using single-crystal X-ray diffraction. Crystallographic studies of the mercury ( Ⅱ ) complex reveal that the complex possesses a five-coordinated geometry that can be best described as a distorted trigonal-bipyramidal. The luminescent properties of ligand L and complex 1 both in solution and in solid state were also studied.