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The title compound,trans-bis(acesulfamato-O)tetraaquazinc(Ⅱ)(I,C_8H_(16)N_2O_(12)S_2Zn), crystallizes in the triclinic system,space group P_1~-with a=5.1638(5),b=8.5338(9),c=9.9583(9) (?),a=74.325(8),β=81.112(7),γ=75.800(8)°,V=407.77(7)(?)~3,Z=1,F(000)=236,R_(int)=0.085, T=296 K,the final R=0.029 and wR=0.078 for 1832 observed reflections with I>2σ(I).The Zn~Ⅱcentre resides on a centre of symmetry and has a distorted octahedral geometry.The basal plane is defined by two carbonyl O atoms of two monodentate trans-oriented acesulfamato ligands and two trans-aqua ligands.The axial positions in the octahedron are occupied by two trans-aqua ligands. Intermolecular O-H…O hydrogen bonds produce R_2~2(8)and R_2~2(16)rings,which lead to two-dimensional polymeric chains.
The title compound, trans-bis (acesulfamato-O) tetraaquazinc (II) (I, C_8H_ (16) N_2O_ (12) S_2Zn) crystallizes in the triclinic system space group P_1 ~ -with a = 5.1638 A = 74.325 (8), β = 81.112 (7), γ = 75.800 (8) °, V = 407.77 (7) Z = 1, F (000) = 236, R_ (int) = 0.085, T = 296 K, the final R = 0.029 and wR = 0.078 for 1832 observed reflections with I> 2σ (I) a center of symmetry and has a distorted octahedral geometry. The basal plane is defined by two carbonyl O atoms of two monodentate trans-oriented acesulfamato ligands and two trans-aqua ligands. The axial positions in the octahedron are occupied by two trans-aqua ligands . Intermolecular OH ... O hydrogen bonds produce R_2 ~ 2 (8) and R_2 ~ 2 (16) rings, which lead to two-dimensional polymeric chains.