NF3 decomposition in the absence of water over Al2O3, Fe2O3, CO3O4 and NiO, and transition metal oxides (Fe2O3, CO3O4 and NiO) coated Al2O3 reagents was investigated. The results show that Al2O3 is an active reagent for NF3 decomposition with 100% conversion lasting for 8.5h at 400℃. Fe2O3, Co2O3 and NiO coated Al2O3 reagents are superior to bare Al2O3, and 5%Co2O3]Al2O3 has a high reactivity with NF3 full conversion maintaining for 10.5 h. It is suggested that the presence of transition metal oxide is beneficial to the reactivity of Al2O3,and results in a significant enhancement in the fluorination of Al2O3.