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以(NH4)6MnMo9O32.6H2O和苯并咪唑为原料,采用常规的水溶液法合成了Waugh型钼酸盐(C7H7N2)5Mn0.5(H2O)2[MnMo9O32].10H2O,并对其进行了单晶结构测定、红外光谱、固体紫外可见漫反射光谱及热重分析。晶体学参数为:单斜晶系,P2(1)/c空间群,a=10.813(6),b=15.848(9),c=36.395(2),β=95.143(10)°,V=6211.8.5(6)3,Z=2,Dc=9.841 g.cm-3,R1=0.0455,wR2=0.1005(I>2σ),GOF=1.032。
Waugh molybdate (C7H7N2) 5Mn0.5 (H2O) 2 [MnMo9O32] .10H2O was synthesized by the conventional aqueous method using (NH4) 6MnMo9O32.6H2O and benzimidazole as raw materials, and its single crystal structure Determination, Infrared Spectroscopy, UV Visible Diffuse Reflectance Spectroscopy and Thermogravimetric Analysis. The crystallographic parameters are monoclinic, P2 (1) / c space group, a = 10.813 (6) , b = 15.848 (9) , c = 36.395 2, β = 95.143 (10) ° , V = 6211.8.5 (6) 3, Z = 2, Dc = 9.841 g.cm-3, R1 = 0.0455, wR2 = 0.1005 (I> 2σ), GOF = 1.032.