本文着重报导对采自我国不同地区和不同成因类型的23个天然萤石样品所进行的喇曼光谱测定和研究结果，大多数样品也同时显示发光谱。研究说明，萤石的喇曼图诺与其成因类型、样品的颜色，特别是所含稀土总量密切相关。低温有利于发光谱线的呈现，而高温则恰恰相反。 This article focuses on Raman spectroscopy and results of 23 natural fluorite samples collected from different regions and different genetic types in our country. Most samples also show the emission spectrum. The research shows that the Laman image of fluorite is closely related to its genetic type, the color of the sample, and especially the total rare earth content. Low temperature is conducive to the appearance of the emission lines, while the high temperature is just the opposite.